book: Synthesis and non-isothermal crystallization behavior of poly(ethylene...

book: Synthesis and non-isothermal crystallization behavior of poly(ethylene phthalate-co-terephthalate)s.: An ... | Byeongdu Lee, Jin Won Lee, ...

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Synthesis and non-...

	Synthesis and non-isothermal crystallization behavior of poly(ethylene phthalate-co-terephthalate)s.: An ... Byeongdu Lee, Jin Won Lee, ... Society of Plastics Engineers, Inc., 2004 - 21 pages
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This digital document is an article from Polymer Engineering and Science, published by Society of Plastics Engineers, Inc. on September 1, 2004. The length of the article is 6061 words. The page length shown above is based on a typical 300-word page. The article is delivered in HTML format and is available in your Amazon.com Digital Locker immediately after purchase. You can view it with any web browser.

From the author: A series of poly(ethylene phthalate-co-terephthalate)s were synthesized by melt polycondensation of ethylene glycol (EG) with dimethyl phthalate (DMP) and dimethyl terephthalate (DMT) in various proportions. The DMT-rich polymers were obtained with reasonably high molecular weights, whereas the DMP-rich polymers were synthesized with relatively low molecular weights due to steric effects associated with the highly kinked DMP monomer. The compositions and thermal properties of the polymers were determined. The copolymers containing DMP in amounts of [less than or equal to] 21 mol% were crystallizable, whereas the other polymers were not. All the polymers exhibited a single glass transition temperature. Analysis of the measured glass transition temperatures and crystal melting temperatures confirmed that the DMT-rich copolymers are random copolymers. The non-isothermal crystallization behaviors of the DMT-rich copolymers were investigated by calorimetry and modified Avrami analysis. The Avrami exponents n were found to range from 2.7 to 3.8, suggesting that the copolymers crystallize via a heterogeneous nucleation and spherulitic growth mechanism; that is, the incorporation of DMP units as the minor component does not change the growth mechanism of the copolymers. In addition, the activation energies of the crystallizations of the copolymers were determined; the copolymers were found to have higher activation energies than the PET homopolymer. Polym. Eng. Sci. 44:1682-1691, 2004. [c] 2004 Society of Plastics Engineers.

Citation Details
Title: Synthesis and non-isothermal crystallization behavior of poly(ethylene phthalate-co-terephthalate)s.
Author: Byeongdu Lee
Publication: Polymer Engineering and Science (Refereed)
Date: September 1, 2004
Publisher: Society of Plastics Engineers, Inc.
Volume: 44 Issue: 9 Page: 1682(10)

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